Burgess reagent, (Methoxycarbonylsulfamoyl)triethylammonium hydroxide
The Burgess reagent is a commercially available compound that has historically found utility as a dehydrating agent. The reagent may also be used to oxidize primary and secondary alcohols to their corresponding aldehydes and ketones in dimethyl sulfoxide.
New Uses for the Burgess Reagent in Chemical Synthesis: …
2004年10月29日 · This article delineates the power of these new reaction manifolds and demonstrates how the use of novel Burgess-type reagents extends the scope of these transformations even further.
Burgess reagent - SpringerLink
2021年1月29日 · The Burgess reagent [methyl N-(triethylammoniumsulfonyl)carbamate], a neutral, white crystalline solid, is efficient at generating olefins from secondary and tertiary alcohols where the first-order thermolytic Ei (during the elimination—the two groups leave at about the same time and bond to each other concurrently) mechanism prevails.
Burgess reagent - chemeurope.com
The Burgess reagent or Methyl N-(triethylammoniumsulphonyl)carbamate is a mild and selective dehydrating reagent often used in organic chemistry [1]. It is used to convert any alcohol with an adjacent proton into an alkene .
Burgess Reagent: From Oblivion to Renaissance in Organic Synthesis
2009年3月1日 · An efficient chemoselective method for the preparation of nitriles from primary amides is described which utilizes methyl (car☐ysulfamoyl)triethylammonium hydroxide inner salt (Burgess reagent...
The Burgess reagent is a carbamate and used for the dehydration of various sec- and tert- alcohols to get the corresponding olefins. Moreover, it also found applications in numerous synthetic transformations in organic chemistry and particularly in medicinal chemistry. Applications of Burgess Reagent in Synthetic organic Chemistry
Burgess reagent | C8H18N2O4S | CID 2724994 - PubChem
Burgess reagent | C8H18N2O4S | CID 2724994 - structure, chemical names, physical and chemical properties, classification, patents, literature, biological activities, safety/hazards/toxicity information, supplier lists, and more.
2016年5月3日 · Burgess reagent was also utilized to promote several other transformations of great synthetic values in medicinal chemistry. In this Atlanchim letter, we will present a brief overview of the uses of this reagent.
Burgess Dehydrating Reagent - Alfa Chemistry
Burgess reagent [methyl N-(triethylaminosulfonyl)carbamate] is a powerful dehydrating agent for secondary and tertiary alcohols. Alfa Chemistry introduces the overview, reaction mechanism, and application cases of Burgess dehydrating reagent.
Recent Advances in the Application of the Burgess Reagent in …
This review focuses on the recent applications of Burgess reagent in the synthesis of organic compounds, with the emphasis, on the total synthesis of natural occurring products. Keywords: Aminoalcohols, Burgess reagent, carbamate, dehydration of alcohols, inner salt, olefination, [methoxycarbonyl-sulfamoyl]triethylammonium hydroxide, sulfamidates.
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